A general asymmetric hydrogenation of a wide range of 2-alkyl- and 2-aryl-substituted quinoxaline derivatives catalyzed by an iridium–difluorphos complex has been developed. Under mild reaction ...

To highlight the high reactivity of the benzylic azide compared to that of its aryl analogue, a multivariate UiO-66 material containing ∼25% 2-azidoterephthalic acid [H 2 bdc-N 3; MTV-UiO-66- (N 3) 25 ...